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Boosting Aerial Object Detection Performance via Virtual Reality Data and Multi-Object Training

https://doi.org/10.1109/IJCNN54540.2023.10191223

Koutsoubis, Nikolas; Naddeo, Kyle; Williams, Garrett; Lecakes, George; Ditzler, Gregory; Bouaynaya, Nidhal C.; Kiel, Thomas (June 2023, IEEE/INNS International Joint Conference on Neural Networks)
DyViR: dynamic virtual reality dataset for aerial threat object detection

https://doi.org/10.1117/12.2663417

Williams, Garrett; Lecakes, George; Almon, Amanda; Koutsoubis, Nikolas; Naddeo, Kyle; Kiel, Thom; Ditzler, Gregory; Bouaynaya, Nidhal (June 2023, Proceedings Volume 12529, Synthetic Data for Artificial Intelligence and Machine Learning: Tools, Techniques, and Applications)
Manser, Kimberly E.; Rao, Raghuveer M.; Howell, Christopher L. (Ed.)
One-Pot Assembly and Synthetic Applications of Geminal Acyl/Alkoxy Tetrasubstituted Allenes

https://doi.org/10.1021/acs.joc.2c01322

Bergstrom, Benjamin D.; Toth-Williams, Garrett; Lo, Anna; Toman, Jeffrey W.; Fettinger, James. C.; Shaw, Jared T. (September 2022, The Journal of Organic Chemistry)

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1,3-Asymmetric Induction in Diastereoselective Allylations of Chiral N -Tosyl Imines

https://doi.org/10.1021/acs.joc.1c02691

Lo, Anna; Gutierrez, David A.; Toth-Williams, Garrett; Fettinger, James C.; Shaw, Jared T. (March 2022, The Journal of Organic Chemistry)

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Desymmetrization of Cyclic Sulfonimidamides by Asymmetric Allylation

https://doi.org/10.1002/anie.202407114

Gutierrez, David_A; Toth‐Williams, Garrett; Laconsay, Croix_J; Yasuda, Michael; Fettinger, James_C; Di_Maso, Michael_J; Shaw, Jared_T (July 2024, Angewandte Chemie International Edition)

Abstract Herein we report the first transition metal‐catalyzed approach to the enantioenriched synthesis of cyclic sulfonimidamides relying on commercially available palladium catalysts and ligands. High‐throughput experimentation (HTE) was employed to identify the optimal catalyst system and solvent. The method is applied to a variety of saturated and unsaturated rings and exhibits the highest selectivity for 2‐substituted allyl electrophiles. The products are further elaborated to complex, tricyclic scaffolds. DFT experiments presented herein highlight the key ligand substrate interactions leading to the high levels of enantioselectivity.
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